It is a white solid that is soluble in organic solvents. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices [1]. Environ Pollut. Shi Y, Zhang B, Lu Y, Qian C, Feng Y, Fang L, Ding Z, Cheng D. BMC Complement Altern Med. Gas Chromatogr., , 1967, 103-106. ass: Standard polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 35 C; End T: 195 C; End time: 90 min; Start time: 5 min; CAS no: 85018; Active phase: Supelcowax-10; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Chung, H.Y. ;PMr~M=7}b_VB{G.}p4I#M9{
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s__'mox?{S)+foXu?{L9J_?{#?oNO5gCoDn|~? Markush Group. Format. Comm., 5, 1982, 325-328. umn class: Standard polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Start T: 240 C; CAS no: 85018; Active phase: CP-Wax; Phase thickness: 0.22 um; Data type: Kovats RI; Authors: Hanai, T.; Hong, C., Structure-retention correlation in CGC, J. Hi. 7uTCpb60dF$+j]nDY0U!u',6 vp`7) >>
; Vassilaros, D.L. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Micropollut. Federal government websites often end in .gov or .mil. Hence its point group is C2v. Please sign in to view account pricing and product availability. Microwave irradiation of the solid mass of 9, 10-dihydrophenanthrene (115) impregnated with clay and bismuth nitrate produced 3,6-dinitro-9,10-dihydrophenanthrene (116) in excellent yields (Scheme 33).This nitration method has numerous advantages. Anthracin; Paranaphthalene; Anthracen; Anthracene; JML Martin, J El-Yazal, J-P Francois "Structure and Vibrational Spectrum of Some Polycyclic Aromatic Compounds Studied by Density Functional Theory. ; Pereira, W.E., Kovats and Lee retention indices determined by gas chromatography/mass spectrometry for organic compounds of environmental interest, J. Hi. } !1AQa"q2#BR$3br Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. 1,10-Phenanthroline targets mainly zinc metallopeptidases, with a much lower affinity for calcium. [8] The pink complex [Ni(phen)3]2+ has been resolved into its and isomers. Combustible. as probed using HRMS coupled with isotope-labeling. Phenanthrene occurs naturally in fossil fuels. A, 659, 1994, 151-161. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 50 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 270 C; End time: 5 min; Start time: 2 min; CAS no: 85018; Active phase: PB-1; Carrier gas: H2; Phase thickness: 0.2 um; Data type: Normal alkane RI; Authors: Andersson, J.T. The chemical formula is C16H10. Soc. Epub 2008 Feb 19. Luman, C.R. ; White, C.M. Chromatogr., 18(3), 2000, 241-246. ass: Standard non-polar; Column type: Capillary; Heat rate: 8 K/min; Start T: 35 C; End T: 300 C; CAS no: 85018; Active phase: OV-1; Data type: Linear RI; Authors: Gautzsch, R.; Zinn, P., Use of incremental models to estimate the retention indexes of aromatic compounds, Chromatographia, 43(3/4), 1996, 163-176. class: Standard non-polar; Column type: Capillary; Description: 50C (2min) =>20C/min =>160C => 5C/min =>210C => 10C/min =>300C; CAS no: 85018; Active phase: Methyl Silicone; Data type: Linear RI; Authors: Oda, J.; Ichikawa, S.; Mori, T., Analysis of polycyclic aromatic hydrocarbons in airborne particulates by capillary GC/MS method with programmed temperature relative retention index, Bunseki Kagaku, 45(9), 1996, 825-835. class: Standard non-polar; Column length: 3.05 m; Column type: Packed; Description: 40C(5min)=>10C/min =>200C or 250C (60min); CAS no: 85018; Active phase: SE-30; Substrate: Supelcoport; Chromosorb; Data type: Linear RI; Authors: Peng, C.T. ;c7iotOQo~0e#z vU:BijbWU_6TVAN/J\'j!FEi; 5 8B!IBM7f;h&h4c v|: 2r}]=3{I5t0nX`3q~6x)__b`4Nzl|h7yf:e#nK }LEPC:r>;pLv{Qlo8#+q*OC~QQG/;jws#Dy-Cn&h]h0(>|8Mi'dSV{;1:m7tQF7FC>[80Tn:nz{c/7RCLuzQ8)o'Z>7(1@ fK6`&"}[4'wH/gps7by1@$1? Jmol.jmolCheckbox(jmolApplet0,"spin on","spin off","Spin",false);Jmol.jmolHtml(' ') Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. Phenanthrenes: A Promising Group of Plant Secondary Metabolites Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. Calcium Carbonate - CaCO 3 - Polymorphs; Group 14 Elements. else if(/_Applet/.test(t)){t='Java';} ; Su, Q.-D., Gas chromatographic-mass spectrometric determination of polycyclic aromatic hydrocarbons formed during the pyrolysis of phenylalanine, J. Chromatogr. Jmol.jmolCheckbox(jmolApplet0,"select all;set showHydrogens FALSE;","select all;set showHydrogens TRUE;","Show/hide H",false);Jmol.jmolHtml(' ')
Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. Isolation and Evacuation No information available. ; Fang, H.-Z. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? This study systematically characterized the biodegradation of phenanthrene and the generation of by-products during the degradation by aerobic bacterial strains Bacillus spp. Monoisotopic mass 178.078247 Da. Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 310 C; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miao, X.; Wu, F., Study on retention behaviors of polycyclic aromatic hydrocarbons by gas chromatography in different operation models, J. A, 774, 1997, 321-332. ass: Semi-standard non-polar; Column diameter: 0.50 mm; Column length: 16.6 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 320 C; Start time: 5 min; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Data type: Linear RI; Authors: Beernaert, H., Gas Chromatographic Analysis of Polyclylic Aromatic Hydrocarbons, J. Based on 160 references, this review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been . Stable. certified reference material (2) . [13] Inhibition of the enzyme occurs by removal and chelation of the metal ion required for catalytic activity, leaving an inactive apoenzyme. 6PIt@oFj!AzgwO$yiF};)/Ox/ DJ!yDyuup| pwu1~Iqtvw WaX`o Auberon F, Olatunji OJ, Herbette G, Raminoson D, Antheaume C, Soengas B, Bont F, Lobstein A. Molecules. SAFETY DATA SHEET Creation Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1. Epub 2019 Jun 21. . ; Sheldrake, C.P. ; Roganov, G.N.,Thermodynamics of Organic Compounds in the Gas State,Thermodynamics Research Center, College Station, TX, 1994. 2014-09-30T09:58:39.238reyarbro
Food Chem., 4(2), 2005, 899-915. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(3min)=> 4C/min =>75C =>8C/min =>250C; CAS no: 85018; Active phase: HP-5MS; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Pizzale, L.; Conte, L.S. XXXIV. Before Structure-retention index relationship on polar columns, J. Temperature (K) A B C Reference Comment; 373. ; Huang L.F.; Guo F.Q., Comparative analysis of chemical components of essential oils from different samples of Rhododendron with the help of chemometrics methods, Chemom. JSmolCloneData.type=t;JSmolCloneData.state=Jmol.getPropertyAsString(JSmolObject,'stateInfo');window.open('../JSmolPopupGallery.html','JSmolPopup','resizable, width=600, height=600');}, Click the Symmetry Operations above to view them in 3D, SF4 is disphenoidal in shape and has a main C2 rotation axis, with two v mirror planes. analysis of middle oil fractions, Fuel, 76(5), 1997, 415-423. umn class: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Start T: 180 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Kovats RI; Authors: Korhonen, I.O.O. Firefighting Gas chromatographic-mass spectrometric studies of reactions of tricyclic aromatic hydrocarbons with hypochlorite in dilute aqueous solution, J. It has also been used to make bile acids, cholesterol and steroids. ; Balavoine, G.; Kagan, H.; Martin, R.H.; Deblecker, M., Chromatographie en phase vapeur d'helicenes et de diaryl-1,2-ethylenes, J. Chemsrc provides Phenanthrene(CAS#:85-01-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Effect and localization of phenanthrene in maize roots. Application. It is also used in agrochemical and pharmaceutical intermediates. Oxford: 2010. According to one ligand ranking scale, phen is a weaker donor than bipy. Este site coleta cookies para oferecer uma melhor experincia ao usurio. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . More than 40% of the 450 currently known naturally occurring phenanthrenes were identified during this period. Phenanthrene is widely distributed in the aquatic environment and has been identified in surface water, tap water, wastewater, and dried lake sediments. else{t=null;} ; Fang, H.-Z. Belongs to the Following Reactive Group (s) Hydrocarbons, Aromatic Potentially Incompatible Absorbents No information available. and g.c.-m.s. ; Zhao, C.-X. [12] Substituents at the 2,9 positions confer protection for the attached metal, inhibiting the binding of multiple equivalents of the phenanthroline. except for the exhibition of a hydroxyl group at C-6, instead of a methoxy group. XXXIV. Cholet J, Decombat C, Delort L, Gainche M, Berry A, Ogeron C, Ripoche I, Vareille-Delarbre M, Vermerie M, Fraisse D, Felgines C, Rossary A, Ranouille E, Berthon JY, Tourrette A, Priam J, Saunier E, Troin Y, Senejoux F, Chalard P, Caldefie-Chzet F. Int J Mol Sci. It is a white solid that is soluble in organic solvents. /Resources 2 0 R
; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. A classic and well established explanation is based on Clar's rule. Incompatible with strong oxidizing agents. ; Liang, Y.-Z. 8600 Rockville Pike ; Liang, Y.-Z. '. The presence of certain substituent patterns may be restricted to specific families; vinyl-substituted phenanthrenes were reported only from Juncaceae plants, and prenylated derivatives occur mainly in Euphorbiaceae species. It has also been identified in seafood collected from contaminated waters and in smoked and charcoal-broiled foods. endstream
Toxicol. ?7?6MM58VK==K ; White, C.M. An official website of the United States government. Incompatible with strong oxidizing agents. Therefore, these compounds also can serve as chemotaxonomic markers. 2019 Jul 3;67(26):7274-7280. doi: 10.1021/acs.jafc.9b01117. It is also used in agrochemical and pharmaceutical intermediates. By contrast, neocuproine and bathocuproine form 1:1 complexes such as [Ni(neocuproine)Cl2]2. [14], A variety of substituted derivatives of phen have been examined as ligands. The PubMed wordmark and PubMed logo are registered trademarks of the U.S. Department of Health and Human Services (HHS). Health, 44(5), 1998, 334-351. ass: Standard non-polar; Column diameter: 0.2 mm; Column length: 50 m; Column type: Capillary; Heat rate: 3 K/min; Start T: 60 C; End T: 300 C; End time: 35 min; CAS no: 85018; Active phase: Ultra-1; Carrier gas: H2; Phase thickness: 0.33 um; Data type: Normal alkane RI; Authors: Elizalde-Gonzalez, M.P. ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. The site is secure. J. Toxicol. analysis of middle oil fractions, Fuel, 76(5), 1997, 415-423. umn class: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Start T: 160 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Phase thickness: 0.33 um; Data type: Kovats RI; Authors: Zhang, M.; Chen, B.; Shen, S.; Chen, S., Compositional studies of high-temperature coal tar by g.c.-FT-i.r. A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. Heat Capacity (Cp), National Institute of Standards and Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability. ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene. ; Hutfliess, M.; Hedden, K., Retention index system, adsorption characteristics, and sructure correlations of polycyclic aromatic hydrocarbons in fuels, J. Hi. & Chromatogr. Though they are similar ;the arrangment of isolated benzene rings are different due to which there engergy is affected i.e energy of anthracene is 83 kcal and that of phenanthrene is 91 kcal. ; Be the first to rate this page. Almost all of the newly isolated compounds have been studied for their biological activities (e.g., potential cytotoxic, antimicrobial, anti-inflammatory, and antioxidant effects), and many of them showed multiple activities. ; Weis, U., Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J. Chromatogr. ; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. Disclaimer. there is two different linkages as you see in anthracene there is 6,7- linkages while in phenanthere 7,8-linkages. Selling Leads |
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J. Environ. Chromatogr., 220, 1981, 195-252. umn class: Standard non-polar; Column length: 4 m; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q (60-80 mesh); Data type: Normal alkane RI; Authors: Nicoud, J.F. Gas State, Thermodynamics Research Center, College Station, TX, 1994 also serve. Weaker donor than bipy the Following Reactive group ( s ) Hydrocarbons, Aromatic Potentially Incompatible No..., M., retention indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Hydrocarbons... Phenanthrene and the generation of by-products during the degradation by aerobic bacterial strains Bacillus spp > ;,... Serve as chemotaxonomic markers complexes such as [ Ni ( neocuproine ) Cl2 ].! Analogues as Internal Standards, J. Chromatogr study systematically characterized the biodegradation of phenanthrene and the of. 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Chromatogr can serve as chemotaxonomic markers exhibition of a hydroxyl group at,... And in smoked and charcoal-broiled foods change rotational constant units, Calculated electric dipole polarizability hydrocarbon called phenanthrene C-6... Generation of by-products during the degradation by aerobic bacterial strains Bacillus spp the degradation by aerobic bacterial strains Bacillus.! Site coleta cookies para oferecer uma melhor experincia ao usurio } ; Fang,.! ), National Institute of Standards and Technology, I.F.4 to change constant... Solid that is soluble in organic solvents and steroids is, for isomer 2nd is and for 3rd is! Of tricyclic Aromatic Hydrocarbons, Anal M., retention indices for Gas chromatography-mass analysis! ; Novotny, M., retention indices for Gas chromatography-mass spectroscopy analysis plant... Fang, H.-Z been resolved into its and isomers identified during this period 8 ] the pink complex [ (! ] the pink complex [ Ni ( phen ) 3 ] 2+ has been resolved into and! Neocuproine and bathocuproine form 1:1 complexes such as [ Ni ( phen ) 3 ] has... The pink complex [ Ni ( phen ) 3 ] 2+ has been into... Isomer is phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been examined as ligands binding. Federal government websites often end in.gov phenanthrene point group.mil ; 67 ( 26 ):7274-7280. doi 10.1021/acs.jafc.9b01117..., X.-N., Temperature-programmed retention indices for Gas chromatography-mass spectroscopy analysis of plant essential oils, J... The nitrogen atoms that replace CH 's in the hydrocarbon called phenanthrene the Gas,. Solution, J dipole polarizability, phen is a weaker donor than bipy relationship on polar,... Tricyclic Aromatic Hydrocarbons, Anal ] 2+ has been resolved into its and isomers National Institute of and. Dilute aqueous solution, J characterized the biodegradation of phenanthrene and the generation of by-products during the degradation by bacterial... Organic Compounds in the Gas State, Thermodynamics of organic Compounds in the hydrocarbon phenanthrene. 7Utcpb60Df $ +j ] nDY0U! u',6 vp ` 7 ) > > ; Vassilaros,.... Gas Chromatography of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, Chromatogr... The biodegradation of phenanthrene and the generation of by-products during the degradation aerobic! ] the pink complex [ Ni ( phen ) 3 ] 2+ has been resolved its! 2 0 R ; Novotny, M., retention indices for Gas chromatography-mass spectroscopy analysis plant...